Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ2N2,N3]dichloridocobalt(II)
Identifieur interne : 000029 ( Maroc/Analysis ); précédent : 000028; suivant : 000030Bis[1-benzyl-2-(1,3-thiazol-4-yl)-1H-benzimidazole-κ2N2,N3]dichloridocobalt(II)
Auteurs : Hicham Gueddar [Maroc] ; Rachid Bouhfid [Maroc] ; El Mokhtar Essassi [Maroc] ; Nabil El Brahmi [Maroc, France] ; Lahcen El Ammari [Maroc]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.
Abstract
In the title compound, [CoCl2(C17H13N3S)2], the CoII atom exhibits a distorted octahedral coordination geometry involving two chloride ligands, one of which is split over two positions [refined site-occupancy ratio = 0.847 (18):0.153 (18)], and four N-atom donors from two 1-benzyl-2-(1,3-thiazol-4-yl)-1
Url:
DOI: 10.1107/S1600536812048751
PubMed: 23476345
PubMed Central: 3588380
Affiliations:
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PMC:3588380Le document en format XML
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<italic>N</italic>
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,<italic>N</italic>
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]dichloridocobalt(II)</title>
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<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name>
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<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
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<front><div type="abstract" xml:lang="en"><p>In the title compound, [CoCl<sub>2</sub>
(C<sub>17</sub>
H<sub>13</sub>
N<sub>3</sub>
S)<sub>2</sub>
], the Co<sup>II</sup>
atom exhibits a distorted octahedral coordination geometry involving two chloride ligands, one of which is split over two positions [refined site-occupancy ratio = 0.847 (18):0.153 (18)], and four N-atom donors from two 1-benzyl-2-(1,3-thiazol-4-yl)-1<italic>H</italic>
-benzimidazole ligands. The two chelate rings including the Co<sup>II</sup>
atom are essentially planar, the maximum deviations from the mean planes being 0.080 (2) and 0.046 (2) Å; the dihedral angle between them is 74.1 (1)°. In both ligands, the thiazole and benzimidazole rings are nearly coplanar, as indicated by the dihedral angles between their planes of 1.16 (8) and 6.29 (7)°. Each pendant benzene ring is almost perpendicular to the benzimidazole molecule to which it is attached; the dihedral angles between their planes are 75.94 (9) and 75.55 (10)°. The crystal structure is stabilized by non-classical C—H⋯Cl hydrogen bonding forming a three-dimensional network.</p>
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